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Classification of Emulsions

An emulsion is a type of colloidal mixture where normally immiscible liquids are combined in a way that maintains their unique chemical identities. In general, there are two parts of an emulsion:

Continuous Phase: the liquid portion of an emulsion in which another liquid is dispersed

Dispersed Phase: the liquid portion that forms tiny droplets that are evenly suspended throughout the continuous phase

The composition of the continuous and dispersed phases offer one way to classify emulsions.

Example: Emulsions of Oil and Water

The schematic below represents two configurations of oil and water emulsions. On the left, an aqueous solution (water-based) is the continuous phase in which droplets of oil are dispersed. Conversely, the right side depicts oil as the continuous phase, with droplets of water dispersed throughout. Again, it is important to note that the components of the continuous phase do not interact with the dispersed phase — nothing is dissolved.

Zooming in, we can see how a surfactant can help stabilize an emulsion by forming micelle “cages” around dispersed droplets. Because of the amphipathic nature of surfactants, the dispersed droplets can be protected from the continuous medium in both scenarios depicted above.

Emulsions are important in our lives, from protecting our lungs to making our skin feel great, to even harvesting pure oil from crude oil so we can use it as fuel. Emulsions allow for a variety of liquids, which can be used in numerous ways that benefit humanity. Let’s dive in to learn more about how emulsions form and what they can do!

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